(μ-Piperazine-1,4-dicarbodithioato-κ4 S,S′:S′′,S′′′)bis[triphenyltin(IV)] dichloromethane solvate
نویسندگان
چکیده
منابع مشابه
(μ-Piperazine-1,4-dicarbodithioato-κ4 S,S′:S′′,S′′′)bis[triphenyltin(IV)] dichloromethane solvate
The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal-bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol-ecule lies across a centre of inversion. The solvent dichloro-methane mol-ecule is disordered about a centre of inversion.
متن کامل[μ-Bis(diphenylphosphanyl-κP)methane]decacarbonyltri-μ-hydrido-trirhenium(I)(3 Re—Re) dichloromethane solvate
In the title compound, [Re(3)(μ-H)(3)(C(25)H(22)P(2))(CO)(10)]·CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis-(diphenyl-phosphan-yl)methane ligand bridges two Re atoms. Neglecting the Re-Re inter-actions, each Re atom is in a slightly distorted octa-hedral coordination environment. The dichloro-methane solvent mol-ec...
متن کاملcatena-Poly[[(tetrahydrofuran-κO)potassium]-di-μ-dimethylamido-κ4 N:N-aluminium-di-μ-dimethylamido-κ4 N:N-potassium-di-μ-dimethylamido-κ4 N:N-aluminium-di-μ-dimethylamido-κ4 N:N]
The title compound, [Al2K2(C2H6N)8(C4H8O)] n , formed during the sonochemical reaction between Al(NMe2)3 and sodium-potassium alloy in the presence of tetra-hydro-furan (THF). Its asymmetric unit has two inequivalent K(+) sites. One site is coordinated by a THF ligand, and crystallizes as a one-dimensional polymer with a backbone of catenated AlN2K rings. A twofold rotation axis bis-ects one K(...
متن کاملCrystal structure of an unknown solvate of (piperazine-κN){5,10,15,20-tetrakis[4-(benzoyloxy)phenyl]porphyrinato-κ4 N}zinc
The title compound, [Zn(C72H44N4O8)(C4H10N2)] or [Zn(TPBP)(pipz] (where TPBP and pipz are 5,10,15,20-tetra-kis-[4-(benzo-yloxy)phen-yl]porphyrinato and piperazine ligands respectively), features a distorted square-pyramidal coordin-ation geometry about the central Zn(II) atom. This central atom is chelated by the four N atoms of the porphyrinate anion and further coordinated by a nitro-gen atom...
متن کاملcatena-Poly[[copper(I)-bis[μ-bis(diphenylphosphino)methane-κ2 P:P′]-copper(I)-μ-2,2′-bipyridine-κ2 N:N′] bis(tetrafluoridoborate) dichloromethane 2.5-solvate]
The title complex, {[Cu(2)(C(10)H(8)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)·2.5CH(2)Cl(2)}(n), contains chains of Cu(I) centres bridged alternately by two (diphenyl-phosphino)methane (dppm) and 4,4'-bipyridine (bpy) ligands. Each Cu(I) atom is coordinated by one N atom of 4,4'-bipyridine (bpy) and two P atoms of two (diphenyl-phosphino)methane (dppm) ligand, and has a trigonal-planar coordination g...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808025890